全文获取类型
收费全文 | 4037篇 |
免费 | 655篇 |
国内免费 | 238篇 |
专业分类
化学 | 265篇 |
晶体学 | 25篇 |
力学 | 1963篇 |
综合类 | 35篇 |
数学 | 312篇 |
物理学 | 2330篇 |
出版年
2024年 | 7篇 |
2023年 | 34篇 |
2022年 | 91篇 |
2021年 | 70篇 |
2020年 | 115篇 |
2019年 | 81篇 |
2018年 | 82篇 |
2017年 | 149篇 |
2016年 | 159篇 |
2015年 | 131篇 |
2014年 | 243篇 |
2013年 | 201篇 |
2012年 | 192篇 |
2011年 | 277篇 |
2010年 | 178篇 |
2009年 | 201篇 |
2008年 | 233篇 |
2007年 | 263篇 |
2006年 | 259篇 |
2005年 | 235篇 |
2004年 | 235篇 |
2003年 | 212篇 |
2002年 | 182篇 |
2001年 | 138篇 |
2000年 | 133篇 |
1999年 | 126篇 |
1998年 | 130篇 |
1997年 | 77篇 |
1996年 | 71篇 |
1995年 | 56篇 |
1994年 | 56篇 |
1993年 | 48篇 |
1992年 | 46篇 |
1991年 | 51篇 |
1990年 | 35篇 |
1989年 | 31篇 |
1988年 | 24篇 |
1987年 | 8篇 |
1986年 | 8篇 |
1985年 | 10篇 |
1984年 | 8篇 |
1983年 | 2篇 |
1982年 | 10篇 |
1981年 | 8篇 |
1980年 | 3篇 |
1979年 | 7篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1971年 | 3篇 |
1957年 | 8篇 |
排序方式: 共有4930条查询结果,搜索用时 15 毫秒
31.
Manipulation of micro-objects have been playing an essential role in biochemical analysis or clinical diagnostics. Among the diverse technologies for micromanipulation, acoustic methods show the advantages of good biocompatibility, wide tunability, a label-free and contactless manner. Thus, acoustic micromanipulations have been widely exploited in micro-analysis systems. In this article, we reviewed the acoustic micromanipulation systems that were actuated by sub-MHz acoustic waves. In contrast to the high-frequency range, the acoustic microsystems operating at sub-MHz acoustic frequency are more accessible, whose acoustic sources are at low cost and even available from daily acoustic devices (e.g. buzzers, speakers, piezoelectric plates). The broad availability, with the addition of the advantages of acoustic micromanipulation, make sub-MHz microsystems promising for a variety of biomedical applications. Here, we review recent progresses in sub-MHz acoustic micromanipulation technologies, focusing on their applications in biomedical fields. These technologies are based on the basic acoustic phenomenon, such as cavitation, acoustic radiation force, and acoustic streaming. And categorized by their applications, we introduce these systems for mixing, pumping and droplet generation, separation and enrichment, patterning, rotation, propulsion and actuation. The diverse applications of these systems hold great promise for a wide range of enhancements in biomedicines and attract increasing interest for further investigation. 相似文献
32.
Ultrasonic-assisted metal droplet deposition (UAMDD) is currently considered a promising technology in droplet-based 3D printing due to its capability to change the wetting and spreading behaviors at the droplet-substrate interface. However, the involved contact dynamics during impacting droplet deposition, particularly the complex physical interaction and metallurgical reaction of induced wetting-spreading-solidification by the external energy, remain unclear to date, which hinders the quantitative prediction and regulation of the microstructures and bonding property of the UAMDD bumps. Here, the wettability of the impacting metal droplet ejected by a piezoelectric micro-jet device (PMJD) on non-wetting and wetting ultrasonic vibration substrates is studied, and the corresponding spreading diameter, contact angle, and bonding strength are also discussed. For the non-wetting substrate, the wettability of the droplet can be significantly increased due to the extrusion of the vibration substrate and the momentum transfer layer at the droplet-substrate interface. And the wettability of the droplet on a wetting substrate is increased at a lower vibration amplitude, which is driven by the momentum transfer layer and the capillary waves at the liquid–vapor interface. Moreover, the effects of the ultrasonic amplitude on the droplet spreading are studied under the resonant frequency of 18.2–18.4 kHz. Compared to deposit droplets on a static substrate, such UAMDD has 31% and 2.1% increments in the spreading diameters for the non-wetting and wetting systems, and the corresponding adhesion tangential forces are increased by 3.85 and 5.59 times. 相似文献
33.
Hua Lei Meixuan Wu Ying Liu Fan Mo Jiayao Chen Shilong Ji Yan Zou Xiaoping Dong 《中国化学快报》2021,32(7):2317-2321
Photocatalysis technology has been proved to be a potential strategy for removal of organic dyes, however high-power light sources are generally necessary to initiate photocatalytic reaction. In this work, we employed an excellent photocatalyst of Bi2WO6 with visible light harvest and meanwhile an intrinsic ferroelectricity, which realized the efficient degradation of organic dye via the synergetic photopiezocatalysis. Through coupling the illumination by a low-power (9 W) LED and the ultrasonic vibration (120 W) by an ultrasonic cleaner, the nanoflower-like Bi2WO6 composed of ultrathin nanosheets showed a much more enhanced photopiezocatalysis performance for purification of organic dye than the individual photocatalysis and piezocatalysis. Furthermore, the high mineralization efficiency and the good durability of the Bi2WO6 catalyst were demonstrated. The possible mechanism of photopiezocatalysis was finally proposed, where the ultrasound-induced piezoelectric field in Bi2WO6 drove photo-generated electrons and holes to diffuse along opposite directions, consequently promoting the separation efficiency of charge carriers. This work indicates that the synergetic photopiezocatalysis by coupling irradiation and ultrasonic vibration is a promising strategy to purify organic pollutants in wastewater. 相似文献
34.
采用传统的熔融法制备了Er~(3+)掺杂的新型铋酸盐玻璃(Li_2O-SrO-ZnO-Bi_2O_3,LSZB),并对其光谱性质进行了表征,分析了玻璃的拉曼光谱、吸收光谱、荧光光谱,利用Judd-Ofelt理论研究了其荧光特性。LSZB玻璃样品中Er~(3+)的~4I_(13/2)→~4I_(15/2)跃迁发射峰位于1.53 μm处,半高宽约为78 nm。样品中Er~(3+)的~4I_(13/2)能级寿命为2.848 ms,量子效率为99.93%,受激发射截面达到9.76×10~(-21)cm~2。以上结果显示,Er~(3+)掺杂LSZB玻璃有良好的光谱特性。 相似文献
35.
研究了一个激光脉冲放大器增益通量系统解的问题.首先讨论了较一般的系统, 然后引入一个同伦映射.再利用映射的性质, 引进一个人工参数, 将求解非线性问题转化为求解一系列线性问题.再逐次地求出对应的线性问题的解, 最后得到了原模型解的近似展开式.可以看出, 同伦映射方法是一个解析的方法.它是通过函数的解析运算并用初等函数来表达近似解,其不同于用离散数值运算的数值计算方法.因此通过同伦映射解, 还可以对它继续进行解析运算, 从而可以进行微分和积分等运算来得到与激光脉冲放大器增益通量相关的其他物理量的性态. 相似文献
36.
37.
《Journal of computational chemistry》2017,38(12):892-900
An accurate potential energy surface of sulfur dioxide, SO2, in its ground electronic state has been determined from ab initio calculations using the coupled‐cluster approach in conjunction with the correlation‐consistent basis sets up to septuple‐zeta quality. The results obtained with the conventional and explicitly correlated coupled‐cluster methods are compared. The role of the core–electron correlation, higher‐order valence–electron correlation, scalar relativistic, and adiabatic effects in determining the structure and dynamics of the SO2 molecule is discussed. The vibration‐rotation energy levels of the 32SO2 and 34SO2 isotopologues were predicted using a variational approach. It was shown that the inclusion of the aforementioned effects was mandatory to attain the “spectroscopic” accuracy. © 2017 Wiley Periodicals, Inc. 相似文献
38.
In this article, we derive error estimates for the semi-discrete and fully discrete Galerkin approximations of a general linear second-order hyperbolic partial differential equation with general damping (which includes boundary damping). The results can be applied to a variety of cases (e.g. vibrating systems of linked elastic bodies). The results generalize pioneering work of Dupont and complement a recent article by Basson and Van Rensburg. 相似文献
39.
李逸豪徐典陈一鸣安东琦李锐 《应用数学和力学》2023,(9):1112-1121
Analytical solutions, with unique research value, can serve as benchmarks for empirical formulas and numerical methods, a tool for rapid parameter analysis and optimization, and a theoretical basis for experimental designs. Conventional analytical methods, e.g., the Lévy solution method, are only applicable to mechanical problems of plates and shells with opposite simply-supported edges, which, however, may fail to obtain analytical solutions for the issues with complex boundary constraints. In recent years, the finite integral transform method for plate and shell problems was developed to deal with non-Lévy-type plates and shells, but it is still infeasible to solve the mixed boundary constrains-induced complex boundary value problems of higher-order partial differential equations. Herein, for the first time, the finite integral transform method was combined with the sub-domain decomposition technique to solve the free vibrations of rectangular thin plates with mixed boundary constraints. The rectangular plate was first divided into 2 sub-domains according to the mixed boundary constraints, and the 2 sub-domains were solved analytically with the finite integral transform method. Finally, the continuity conditions were introduced to obtain the analytical solution of the original problem. Based on the side spot-welded cantilever plates commonly used in engineering, the free vibration problem of a rectangular thin plate with 1 edge subjected to clamped-simply supported constraints and the other 3 edges free, was analyzed. The obtained natural frequencies and mode shapes are in good agreement with those from the finite element method as well as the solutions in literature, thus verifying the accuracy of the proposed method. The solution procedure of the finite integral transform method can be implemented based on the governing equations without any assumption of the solution form. Therefore, this strict analytical method is widely applicable to complex boundary value problems of higher-order partial differential equations for such mechanical problems of plates and shells. © 2023 Editorial Office of Applied Mathematics and Mechanics. All rights reserved. 相似文献
40.
基于电磁振动上料的茶梗和昆虫异物近红外光谱和荧光图像在线检测研究 总被引:1,自引:0,他引:1
茶叶是大众青睐的健康饮品之一,但茶叶在机器采收和加工过程中,容易混入茶梗和昆虫异物,污染茶叶、影响其质量安全,是未来应防范和检测的重点。X射线成像技术,根据食品基质和异物的密度差实施检测,广泛适用于金属异物并延伸至高密度塑料,但对于茶梗、昆虫这类低密度有机异物尚不适用,所以迫切需要研发新型无损检测技术和方法。针对片状茶叶重叠、遮掩异物的问题,提出了电磁振动上料辅助近红外光谱和荧光图像的检测方案,进行绿茶中的内源性异物茶梗和外源性异物昆虫的在线检测研究。通过电磁振动上料辅助近红外光谱和荧光成像系统,采集了600~1 050 nm范围的近红外光谱600条和RGB-N四通道图像各65幅。采用451条光谱进行建模,其余149条光谱作为预测集,评估模型的性能,比较了去趋势(Detrending)、多元散射校正(MSC)、标准正态变换(SNV)、变权重正态变换(VSN)、迭代自适应加权惩罚最小二乘法(airPLS)、不对称最小二乘法(ALS)、光程估计与校正(OPLEC)等不同光谱预处理方法的处理效果,其中OPLEC能较好地消除散射效应,偏最小二乘判别分析(PLS-DA)模型的正确识别率由78%提... 相似文献